A man has been refused bail to appear in court after a woman's body was found in a home. Photo: Ronnie Amini/AAP PHOTOS

A 37-year-old man faces murder charges after a woman's body was found with a gunshot wound.

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A sawn-off shotgun and ammunition were allegedly found in the man's car when NSW Police took him into custody in the Hunter Valley region on Saturday night.

The arrest came after emergency services were called to a home in Kearsley on Friday night.

Officers found a 39-year-old woman dead at the residence.

Police on Saturday alerted the public that they wanted to speak wit

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